一类非线性奇摄动分数阶微分方程的渐近解

研究了一类奇摄动非线性分数阶微分方程边值问题.在适当的条件下,首先求出了原问题的外部解,然后利用伸长变量、合成展开法和幂级数展开理论构造出解的边界层项,并由此得到解的渐近展开式.最后利用微分不等式理论,讨论了问题解的渐近性态,得到了原问题解的一致有效的渐近估计式.     

A New Capillary Electrophoresis Apparatus with Piezoelectric Ceramics High Voltage Source and Amperometric Detector

IntroductionHighperformancecapiliar}'electrophoresis(HPCE)isanewanalyticaltechnology'rapidly'developedinrecentyears.Withtheadvantagesofsmallsample.highsensitivity,highresolution.rapidanalysisandverycheaprunning,ithasbeenappliedinchemistry'.lifescienc...     

A new theory for symmetry orbital and tensor (Ⅱ)——Symmetric reduction of molecular integrals and self-consistent field calculations

The symmetry orbital-symmetry orbital tensor method is applied to the evaluation of molecular integrals (one-electron and two-electron integrals) and the symmetry-orbital-tensor and self-consistent-field (SOT-SCF) calculations. A calculation scheme is proposed to simplify the evaluation of integrals and a key equation is derived to reduce the computation efforts in SCF iterations. According to the key equation, compared with the traditional SCF method, the computation efficiencies including CPU timing and external disk (or internal memory) requirement increase in the magnitude of the square of the order of a point group. The new SOT method is expected to be useful in the theoretical calculations of large molecular systems of high point group symmetries.     

一类具有摄动边界的弱非线性反应扩散方程

研究了具有摄动边界的非线性反应扩散方程的问题.在适当的条件下,利用微分不等式理论,讨论了问题的渐近解.     

吡氟禾草灵的高效液相色谱法拆分与测定

在流动相为正庚烷-异丙醇-三氟乙酸(99.3:0.5:0.2,体积比),流速为0.6 mL·min-1,检测波长为273 am,柱温为10℃的分析条件下,利用手性色谱柱Nucleosil chiral-2实现了吡氟禾草灵对映体的手性分离,在优化的色谱分离条件下,R-型异构体的峰面积与其对应浓度之间保持线性关系,其对应的线性回归方程为A=(236.30ρ 1.94)×100,其相关系数为0.9991.据此可定量测定R型异构体.     

Asymptotic solution for EI Nino-southern oscillation of nonlinear model

A class of nonlinear coupled system for El Nino-Southern Oscillation(ENSO) model is considered.Using the asymptotic theory and method of variational iteration,the asymptotic expansion of the solution for ENSO models is obtained.     

Crystal Transformation of Nylon 11 Using in situ WAXD

Nylon I I is a high-performance semicrystalline polymer which was used widely in manyfields. In recent years, the curious ferroelectric and piezoelectric propel'ties of nylon I Iwere foundl'2. It is well known that piezoelectricity is related to the crystal form ofNylon I 1.The sample was mounteds in a capillary (diameter was Zmm) within a small ovenwith mica windows. The scattered intensity was recorded from Q = 0.2 to 6.5 A-] (Q =ursine/~) using steps of AQ=o.o5A-'. The values of the p…     

几种常见阴离子的高效毛细管电泳-电导分离检测

采用柠檬酸-柠檬酸钠作为缓冲体系,使用负高压,对Cl-、NO3-、HCO3-、H2PO4-几种常见阴离子进行了分离检测,研究了缓冲剂的种类、浓度、pH值及操作电压对分离的影响;在选定的条件下,定量线性范围为Cl-5.0×10-5～2.5×103md/L,NO3-6.0×10-5～2.0×10-3mol/L,HCO3-1.0×10-5～2.0×10-3mol/L,H2PO4-6.0×10-5～1.0×10-3mol/L;检出限为Cl-1.5×10-5mol/L,NO3-3.0×10-5mol/L,HCO3-1.0×10mol/L,H2PO4-2.0×10-5mol/L;4种离子的RSD(n=6)分别为3.1%、33%、2.6%和2.9%;应用选定条件对自来水样品进行了分析,结果令人满意.     

贵金属—GaAs(110)界面价带紫外光电子谱

本文研究了贵金属-CaAs(110)界面形成过程中hν=21.2eV和40.8eV的价带光电子谱的演化,在小于0.5单原子层淀积金属时,观察到所谓原子样Ag5s和Au6s态。大约从10埃到几十埃的淀积金属范围内,发现贵金属价带发射极大值现象。用金属原子团的形成、岛状生长与界面反应相关的观点讨论了实验结果。 关键词：